Synthesis, structures and dynamic NMR spectra of η 6 -hexaethylbenzene complexes of ruthenium(0) and ruthenium(II).
Date
2002
Authors
Baldwin, Richard
Bennett, Martin
Hockless, David
Pertici, Paolo
Verrazzani, Alessandra
Barretta, Gloria
Marchetti, Fabio
Salvadori, Piero
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
On reaction with the labile naphthalene complex [Ru(η6-C10H8)(η4-1, 5-COD)], hex-3-yne undergoes stoichiometric cyclotrimerisation to form the hexaethylbenzene-ruthenium(O) complex [Ru(η6-C6Et6)(η4-1, 5-COD)] 1. In the solid state and in solution the
Description
Keywords
Keywords: Band structure; Benzene; Chemical bonds; Complexation; Conformations; Crystal structure; Crystalline materials; Electrolytes; Infrared spectroscopy; Nuclear magnetic resonance spectroscopy; Solutions; Synthesis (chemical); Arene metal bond; Crystalline ad
Citation
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Source
Dalton Transactions
Type
Journal article