Five-Coordinate [Pt II (bipyridine) 2 (phosphine)] n+ Complexes: Long-lived intermediates in ligand substitution reactions of [Pt(bipyridine) 2 ] 2+ with phosphine ligands
The reaction of [Pt(N-N)2]2+ [N-N = 2,2′-bipyridine (bpy) or 4,4′-dimethyl-2,2′-bipyridine (4,4′-Me2bpy)] with phosphine ligands [PPh3 or PPh(PhSO3)2 2-] in aqueous or methanolic solutions was studied by multinuclear (1H, 13C, 31P, and 195Pt) NMR
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