Rationalizing the 1.9 Å crystal structure of photosystem II - a remarkable Jahn-Teller balancing act induced by a single proton transfer

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Gatt, Phillip
Petrie, Simon
Stranger, Robert
Pace, Ronald

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Wiley-VCH Verlag GMBH

Abstract

Balancing act: DFT calculations show that the structures of the water-oxidizing complex in the two most recent single crystal XRD studies of photosystem II at 2.9 Å and 1.9 Å resolution are tautomers related by a single proton transfer. The anomalous ox

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Angewandte Chemie International Edition

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2037-12-31