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Sillen-Aurivillius intergrowth phases as templates for naturally layered multiferroics

Liu, S.; Miiller, W.; Liu, Yun; Avdeev, Maxim; Ling, Chris David


The ferroelectric Sillen-Aurivillius phase Bi5PbTi3O14Cl, a layered structure containing three-layer perovskite-type blocks, has been modified by substituting magnetic transition metal cations M3+ = Cr3+, Mn3+, or Fe3+ for1/3 of the Ti4+ cations, accompanied by co-doping of Bi3+ for Pb2+. The aim of the modification was to produce naturally layered ferroelectromagnetic compounds. Rietveld refinements against high-temperature synchrotron X-ray powder diffraction data show that the resulting new...[Show more]

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Chemistry of Materials
DOI: 10.1021/cm302342v


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