Osmium-catalyzed vicinal oxyamination of alkenes by N-(4-Toluenesulfonyloxy) carbamates
Date
2012
Authors
Masruri, Masruri
Willis, Anthony
McLeod, Malcolm
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Publisher
American Chemical Society
Abstract
N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.
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Keywords
Keywords: Catalyst loadings; Nitrogen sources; Protecting group; Substituted alkene; Trisubstituted alkenes; Catalysis; Organic compounds; Osmium; Olefins; alkene derivative; amine; carbamic acid derivative; n (4 toluenesulfonyloxy)carbamic acid derivative; nitroge
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Source
Journal of Organic Chemistry
Type
Journal article
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2037-12-31
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