Osmium-catalyzed vicinal oxyamination of alkenes by N-(4-Toluenesulfonyloxy) carbamates
N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.
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|Source:||Journal of Organic Chemistry|
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