Osmium-catalyzed vicinal oxyamination of alkenes by N-(4-Toluenesulfonyloxy) carbamates
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Masruri, Masruri; Willis, Anthony; McLeod, Malcolm
Description
N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.
Collections | ANU Research Publications |
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Date published: | 2012 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/67302 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/jo301372y |
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01_Masruri_Osmium-catalyzed_vicinal_2012.pdf | 851.76 kB | Adobe PDF | Request a copy |
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