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Osmium-catalyzed vicinal oxyamination of alkenes by N-(4-Toluenesulfonyloxy) carbamates

Masruri, Masruri; Willis, Anthony; McLeod, Malcolm

Description

N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/67302
Source: Journal of Organic Chemistry
DOI: 10.1021/jo301372y

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