Iridium(III) Cp* complexes for the efficient hydroamination of internal alkynes
A series of iridium(III) and rhodium(III) 1,2,3,4,5- pentamethylcyclopentadienyl (Cp*) complexes of the type [M(Cp*)(LL)Cl]BPh4 were synthesized, where LL is a chelating diimine or mixed pyrazolyl-phosphine or pyrazolyl-N-heterocyclic carbene donor ligand. The majority of these complexes were characterized by X-ray crystallography, allowing for a detailed comparison of their structural properties. These complexes were shown to yield active hydroamination catalysts upon in situ abstraction of...[Show more]
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