Mechanical properties of a metal-organic framework containing hydrogen-bonded bifluoride linkers
Date
2013
Authors
Li, Wei
Mangalampalli, S.R.N. Kiran
Manson, Jamie L
Schlueter, John A
Thirumurugan, A
Ramamurty, U
Cheetham, Anthony K
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Publisher
Royal Society of Chemistry
Abstract
We report the mechanical properties of a framework structure, [Cu 2F(HF)(HF2)(pyz)4][(SbF6) 2]n (pyz = pyrazine), in which [Cu(pyz)2] 2+ layers are pillared by HF2 - anions containing the exceptionally strong F-H⋯F hydrogen bonds. Nanoindentation studie
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Keywords
Keywords: fluoride; metal organic framework; pyrazine; anisotropy; article; atomic force microscopy; crystal structure; hardness; hydrogen bond; Young modulus; Copper; Fluorides; Hydrogen Bonding; Organometallic Compounds; Pyrazines
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Chemical Communications
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Journal article
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2037-12-31
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