Skip navigation
Skip navigation

Allenylphosphonium Complexes of Rhodium and Iridium

Cade, Ian; Colebatch, Annie; Hill, Anthony; Willis, Anthony


The propargylic salt [Ph3PCH2C≡CH]PF 6 ([1]PF6) undergoes a facile rearrangement to the allenyl isomer [Ph3PCH=C=CH2]PF6 ([2]PF6) upon coordination to rhodium and iridium. The η2- allenylphosphonium salts [IrX(η2-CH2=C=CHPPh 3)(CO)(PPh3)2]PF6 (X = Cl,

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
Source: Organometallics
DOI: 10.1021/om500450e


File Description SizeFormat Image
01_Cade_Allenylphosphonium_Complexes_2014.pdf1.03 MBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  20 July 2017/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator