Heterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes
Date
2012
Authors
Hill, Anthony
Sharma, Manab
Willis, Anthony
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Publisher
American Chemical Society
Abstract
The sequential treatment of [W(≡CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) withnBuLi and [NiCl2(PEt3)2] initially affords the bridging carbido complex [WNi(μ-C)(CO)2(PEt3)2Cl{HB(pzMe2)3}], which is however unstable and isomerizes cleanly to the bridgin
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Keywords
Keywords: CBr; Sequential treatments; Tungsten compounds; Chlorine compounds
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Source
Organometallics
Type
Journal article
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2037-12-31
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