The Use of Spin Traps for the Kinetic Investigation of Elementary Events of Pseudoliving Radical Reversible Addition-Fragmentation Chain-Transfer Polymerization

Date

2011

Authors

Golubev, Vladimir
Filippov, Anatoly
Chernikova, Elena
Coote, Michelle
Lin, Ching-Yeh
Gryn'ova, Ganna

Journal Title

Journal ISSN

Volume Title

Publisher

MAIK Nauka-Interperiodica

Abstract

The spin-trapping technique is used for the first time to study the kinetics and mechanism of addition and fragmentation elementary events in reversible addition-fragmentation chain-transfer pseudoliving radical polymerization. As shown by the example of

Description

Keywords

Keywords: Addition-fragmentation; Benzyl dithiobenzoate; Chain-transfer agents; Fragmentation reactions; Kinetic investigations; Kinetics and mechanism; Model reactions; Orders of magnitude; Poly(n-butyl acrylate); Reversible addition fragmentation chain transfer;

Citation

Source

Polymer Science: Series C

Type

Journal article

Book Title

Entity type

Access Statement

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Restricted until

2037-12-31