Intramolecular cycloaddition reactions of cis-1,2-dihydrocatechol derivatives incorporating C3 tethered diazoketones, nitrile oxides and azides: stereocontrolled routes to enantiomerically pure spiro[5.5]undecanes and related systems
Date
2013
Authors
Reekie, Tristan
Banwell, Martin
Willis, Anthony
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American Chemical Society
Abstract
A series of enantiomerically pure cis-1,2-dihydrocatechol derivatives incorporating C3-tethered diazoketone, nitrile oxide, or azide residues has been prepared from the precursor iodide 7 using Negishi cross-coupling reactions. Such derivatives, including
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Keywords: Diazoketones; Intramolecular cycloaddition reactions; Negishi cross-coupling; Nitrile oxides; Related systems; Stereo-selective; Cycloaddition; Nitrogen oxides; Enantiomers; azide; catechol derivative; fused alicyclic compound; ketone derivative; nitrile
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Journal of Organic Chemistry
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Journal article
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2037-12-31
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