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Intramolecular cycloaddition reactions of cis-1,2-dihydrocatechol derivatives incorporating C3 tethered diazoketones, nitrile oxides and azides: stereocontrolled routes to enantiomerically pure spiro[5.5]undecanes and related systems

Reekie, Tristan; Banwell, Martin; Willis, Anthony

Description

A series of enantiomerically pure cis-1,2-dihydrocatechol derivatives incorporating C3-tethered diazoketone, nitrile oxide, or azide residues has been prepared from the precursor iodide 7 using Negishi cross-coupling reactions. Such derivatives, including

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/62109
Source: Journal of Organic Chemistry
DOI: 10.1021/jo400952u

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