Organoactinides promote the dimerization of aldehydes: Scope, kinetics, thermodynamics, and calculation studies
Date
2011
Authors
Sharma, Manab
Andrea, Tamar
Brookes, Nigel J
Yates, Brian F
Eisen, Moris S.
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American Chemical Society
Abstract
Surprising catalytic activities have been found for the actinide complexes Cp*2ThMe2 (1), Th(NEtMe)4 (2), and Me2SiCp″2Th(C4H9)2(3) toward oxygenated substrates. During the catalytic dimerization of benzaldehydes to their corresponding esters, complexes
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Keywords: Actinide complex; Catalytic activity; Catalytic cycles; Electron withdrawing group; First order; Kinetic study; Mechanistic studies; Methoxybenzaldehyde; Nitrobenzaldehyde; Rate equations; Thermodynamically stable; Transition state; Activation energy; Ald
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Journal of the American Chemical Society
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Journal article
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2037-12-31
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