Oligomerization of α-olefins by the dimeric nickel bisamido complex [Ni{1-N(PMes 2 -N(μ-PMes 2 )C 6 H 4 -κ 3 N , N' , P ,-κ 1 P' }] 2 activated by methylalumoxane (MAO)
Date
2008
Authors
Majoumo-Mbe, Felicite
Lonnecke, Peter
Volkis, Victoria
Sharma, Manab
Eisen, Moris S.
Hey-Hawkins, Evamarie
Journal Title
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Publisher
Elsevier
Abstract
The reaction of Li2[1,2-{N(PMes2)}2C6H4], formed in situ from n-BuLi and the corresponding amines, with 1 equiv. of [NiBr2(DME)] gives [Ni{1-N(PMes2)-2-N(μ-PMes2)C6H4-κ3N,N′,P-κ1P′}]2 (1). After activation by methylalumoxane (MAO), 1 is a highly ac
Description
Keywords
Keywords: Lithium; Microfluidics; Nickel; Olefins; Oligomerization; Nickel alloys a-Olefins; Nickel complex; Oligomerization reaction; P,N ligand
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Source
Journal of Organometallic Chemistry
Type
Journal article
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2037-12-31