Facile syntheses and tunable non-linear optical properties of heterothiometallic clusters with [MS 4 Ag 2 ] units (M=Mo, W).
Date
2010
Authors
Zhang, Jinfang
Meng, Suci
Song, Yinglin
Zhao, Huajian
Li, Jianghua
Qu, Gaoju
Sun, Liang
Zhang, Chi
Humphrey, Mark
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Volume Title
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Wiley-VCH Verlag GMBH
Abstract
A not-so-innocent counterion: A facile synthetic method has been successfully developed to construct two unusual discrete, octanuclear planar "open" distorted-square M/S/Ag clusters {[Sr(DMAC)6] 2[M4S16Ag4]} (M=Mo, W; DMAC=N,N'-dimethylacetylamide) and a
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Keywords
Keywords: Chalcogens; Counterions; Density-functional calculations; Double chain; Facile synthesis; Non-linear optical properties; Optical limiting; Structure elucidation; Synthetic methods; Third-order; Z-scan experiment; Density functional theory; Nonlinear optic chalcogens; density functional calculations; nonlinear optics; structure elucidation; synthetic methods
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Source
Chemistry, A European Journal
Type
Journal article
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2037-12-31
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