Phosphine complexes of an enantiomerically pure, atropisomeric arsenium ion
Date
2012
Authors
Kilah, Nathan
Wild, Stanley (Bruce)
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
The first enantiomerically pure secondary iodoarsine has been prepared by ring closure of (aR)-[{Li(TMEDA)}2{2,2′-bis(methylene)-1, 1′-binaphthylyl}] with dichlorophenylarsine, followed by disproportionation of the resulting seven-membered (aR)-phenyl
Description
Keywords
Keywords: Absolute configuration; Air-stable; Arsenic atom; Binaphthyl; Complex cation; Diastereomers; Disproportionations; H NMR spectra; Hexafluorophosphates; Methoxymethyl; Methylene groups; NMR spectrum; P-chiral phosphines; Phosphine complex; Phosphine exchang
Citation
Collections
Source
Organometallics
Type
Journal article
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31