Phosphino and Phosphonito Carbyne Complexes: [Mo(≡CX)(CO) 2 {HB(pzMe 2 ) 3 }] (X = PPh 2 , P(:O)(OEt) 2 ; pz = Pyrazol-1-yl).

Date

2009

Authors

Cordiner, Richard
Gugger, Paul
Hill, Anthony
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The phosphinocarbyne complex [Mo(≡CPPh2)(CO)2{HB(pzMe 2)3}] is obtained by successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] with nBuLi and ClPPh2. An alternative approach to phosphorus-functionalized carbyne complexes involves the palladium-mediate

Description

Keywords

Keywords: Alternative approach; Carbyne complexes; CBr; Functionalized; Mediated reactions; Phosphorus atom; Bits; Hysteresis motors; Molybdenum; Palladium; Palladium compounds; Phosphorus; Molybdenum compounds

Citation

Source

Organometallics

Type

Journal article

Book Title

Entity type

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Restricted until

2037-12-31