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Experimental and computational studies into an ATPH-promoted exo -Selective IMDA reaction: A short total synthesis of Δ 9 -THC

Pearson, Emma; Kanizaj, Nicholas; Willis, Anthony; Paddon-Row, Michael; Sherburn, Michael

Description

(Figure Presented) Reversal of fortune: The inherent cis stereoselectivity of an intramolecular Diels-Alder reaction is reversed through promotion with aluminum tris(2,6-diphenylphenoxide) (ATPH), allowing a total synthesis of the natural product Δ 9-tet

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
URI: http://hdl.handle.net/1885/57445
Source: Chemistry, A European Journal
DOI: 10.1002/chem.201001176

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