Pyrazolyl- N -heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity
Date
2009
Authors
Page, Michael
Wagler, Jorg
Messerle, Barbara Ann
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Royal Society of Chemistry
Abstract
A series of bidentate 1-(1-pyrazolylmethyl)-substituted NHC ligands (13a-c, 14a-c and 15a-c) were synthesised with substituents of varying steric bulk incorporated adjacent to the donor atoms. These ligands were coordinated to rhodium(I) to give a series
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Keywords
Keywords: Catalytic activity; Complex structure; Donor atoms; Hydrogenation catalyst; Metal bounds; N-heterocyclic carbene complex; NHC ligands; Pyrazolyl; Single crystal x-ray diffraction; Solid-state structures; Steric bulk; Catalysis; Catalyst activity; Hydrogen
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Dalton Transactions
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Journal article
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2037-12-31
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