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Reactions of [Ru(CO) 2 (PPh 3 ) 3 ] with alkynylphosphonium salts: a phosphinoallene complex

Ang, Wee; Cordiner, Richard; Hill, Anthony; Perry, Tamara; Wagler, Jorg

Description

[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a comple

dc.contributor.authorAng, Wee
dc.contributor.authorCordiner, Richard
dc.contributor.authorHill, Anthony
dc.contributor.authorPerry, Tamara
dc.contributor.authorWagler, Jorg
dc.date.accessioned2015-12-10T22:40:17Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/57407
dc.description.abstract[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a comple
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Allenyl; Crystallographic data; Spectroscopic data
dc.titleReactions of [Ru(CO) 2 (PPh 3 ) 3 ] with alkynylphosphonium salts: a phosphinoallene complex
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume28
dc.date.issued2009
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB399
local.type.statusPublished Version
local.contributor.affiliationAng, Wee, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCordiner, Richard, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPerry, Tamara, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue18
local.bibliographicCitation.startpage5568
local.bibliographicCitation.lastpage5574
local.identifier.doi10.1021/om900621v
dc.date.updated2016-02-24T10:43:03Z
local.identifier.scopusID2-s2.0-70349331042
local.identifier.thomsonID000269892300030
CollectionsANU Research Publications

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