Skip navigation
Skip navigation

Organobimetallic Ru II -Re I 4-ethynylpyridyl complexes: structures and non-linear optical properties

Ge, Qingchun; Corkery, Timothy; Samoc, Marek; Hor, T S Andy; Humphrey, Mark

Description

A series of heterobimetallic complexes, [RuCp(CCpy-4)(P-P)][Re(CO) 3(N-N)]+ (P-P = dppf, N-N = bpy 5, Me2bpy 6, tBu2bpy 7, phen 8, tpy 9; P-P = 2PPh3, N-N = bpy 10) have been obtained from Lewis addition between the metalloligands [RuCp(CCpy-4)(P-P)] (P-P = dppf 1; 2PPh32) and solvent-stabilised fac-[Re(CH3CN)(CO)3(N-N)]+. All new complexes 5-10, together with fac-[ReBr(CO)3(tpy)] (3) and fac-[Re(CH 3CN)(CO)3(tpy)][PF6] (4), are characterized by solution spectroscopy; 3 and 5-9 are also...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/57099
Source: Dalton Transactions
DOI: 10.1039/b902800e

Download

File Description SizeFormat Image
01_Ge_Organobimetallic_Ru_II_-Re_I__2009.pdf464.33 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  12 November 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator