Organobimetallic Ru II -Re I 4-ethynylpyridyl complexes: structures and non-linear optical properties
Ge, Qingchun; Corkery, Timothy; Samoc, Marek; Hor, T S Andy; Humphrey, Mark
A series of heterobimetallic complexes, [RuCp(CCpy-4)(P-P)][Re(CO) 3(N-N)]+ (P-P = dppf, N-N = bpy 5, Me2bpy 6, tBu2bpy 7, phen 8, tpy 9; P-P = 2PPh3, N-N = bpy 10) have been obtained from Lewis addition between the metalloligands [RuCp(CCpy-4)(P-P)] (P-P = dppf 1; 2PPh32) and solvent-stabilised fac-[Re(CH3CN)(CO)3(N-N)]+. All new complexes 5-10, together with fac-[ReBr(CO)3(tpy)] (3) and fac-[Re(CH 3CN)(CO)3(tpy)][PF6] (4), are characterized by solution spectroscopy; 3 and 5-9 are also...[Show more]
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