Isolation of trans -2,5-Bis(methoxycarbonyl)ruthenacyclopentane by Oxidative Coupling of Methyl Acrylate on Ruthenium(0) as an Active Intermediate for Tail-to-Tail Selective Catalytic Dimerization
Date
2009
Authors
Hirano, Masafumi
Sakate, Yumiko
Komine, Nobuyuki
Komiya, Sanshiro
Bennett, Martin
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Volume Title
Publisher
American Chemical Society
Abstract
The trans-bis(methoxycarbonyl)ruthenacyclopentane complex [trans-Ru{C 2H{C(O1)OMe}C3H2C4H 2C5H{C(O2)OMe}-K1C 2,K1O1,K1C5,μ-K 1O2}(η4-1,5-COD)]2 (2) and the acetonitrile adduct Ru[C2H(CO2Me)CH2CH 2CH(CO2Me)-K1 C2,K1 C5](η4-1,5-COD)(NCMe)2 (3) have been
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Keywords
Keywords: Methyl acrylates; Oxidative couplings; Acetonitrile; Naphthalene; Ruthenium; Dimerization
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Organometallics
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Journal article
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2037-12-31
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