Electrochemical and chemical oxidation of [Pt 2 (μ-pyrophosphite) 4 ] 4- revisited: characterization of a nitrosyl derivative, [Pt 2 (μ pyrophosphite) 4 (NO)] 3-
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Bennett, Martin
Bhargava, Suresh Kumar
Bond, Alan M
Bansal, Vipul
Forsyth, C M
Guo, Si-Xuan
Priver, Steven H
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American Chemical Society
Abstract
Electrochemical studies of the salts [cat] 4[Pt 2(μ-pop) 4] (cat + = Bu 4N + or PPN + [Ph 3P=N=PPh 3] +; pop = pyrophosphite, [P 2O 5H 2] 2-) have been carried out in dichloromethane. In agreement with published studies of K 4[Pt 2(μ-pop) 4] in water an
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Inorganic Chemistry
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2037-12-31
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