Skip navigation
Skip navigation

Triphenylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Salts

Kilah, Nathan; Petrie, Simon; Stranger, Robert; Wielandt, Wolfram; Willis, Anthony; Wild, Stanley (Bruce)


Two series of triphenylphosphine-stabilized diphenyl-arsenium, -stibenium, and -bismuthenium salts of the types [(Ph3P)EPh2]PF 6 (where E = As, Sb, Bi) and [(Ph3P)2EPh 2]PF6 (where E = Sb, Bi) have been synthesized and their structures and bonding investigated by X-ray crystallography and density functional theory at the PBE/TZP level. The coordination geometries around the central group 15 elements are distorted trigonal pyramidal in the mono(triphenylphosphine) complexes and distorted...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Organometallics
DOI: 10.1021/om700512h


File Description SizeFormat Image
01_Kilah_Triphenylphosphine-Stabilized_2007.pdf522.49 kBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  20 July 2017/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator