Triphenylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Salts
Two series of triphenylphosphine-stabilized diphenyl-arsenium, -stibenium, and -bismuthenium salts of the types [(Ph3P)EPh2]PF 6 (where E = As, Sb, Bi) and [(Ph3P)2EPh 2]PF6 (where E = Sb, Bi) have been synthesized and their structures and bonding investigated by X-ray crystallography and density functional theory at the PBE/TZP level. The coordination geometries around the central group 15 elements are distorted trigonal pyramidal in the mono(triphenylphosphine) complexes and distorted...[Show more]
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