Local v/a variations as a measure of structural packing frustration in bicontinuous mesophases, and geometric arguments for an alternating Im3m (I-WP) phase in block copolymers with polydispersity

Date

2007

Authors

Schroeder, Gerd
Fogden, Andrew
Hyde, Stephen

Journal Title

Journal ISSN

Volume Title

Publisher

Springer

Abstract

This article explores global geometric features of bicontinuous space-partitions and their relevance to self-assembly of block-copolymers. Using a robust definition of 'local channel radius', based on the concept of a medial surface [Schröder et al., Eur

Description

Keywords

Keywords: Geometric features; Gyroid geometry; Polymolecular chain stretching; Volume to surface ratios; Molecular dynamics; Molecular weight distribution; Polydispersity; Self assembly; Surface structure; Block copolymers

Citation

Source

European Physical Journal B

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31