In Search of Fulminate Analogues: Ln M≡CP=NR
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Frogley, Benjamin; Hill, Anthony
; Shang, Rong; Sharma, Manab; Willis, Anthony
Description
The "CPNR" ligand may be viewed as being isolobal with fulminate, CNO; however, attempts to prepare a complex of such a ligand resulted instead in a range of novel imino and aminophosphinocarbyne complexes. Sequential treatment of [Mo(≡CBr)(CO)2 (Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) with nBuLi and ClP=NMes* (Mes*=C6 H2 tBu3 -2,4,6) afforded mixtures of the complexes [Mo(≡CPnBuNHMes*)(CO)2 (Tp*)] and traces of the bimetallic products [Mo2 {μ2 -C2 P2 O(NHMes)2 }(CO)4 (Tp*)2 ] and [Mo2...[Show more]
Collections | ANU Research Publications |
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Date published: | 2020-07-17 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/217022 |
Source: | Chemistry - A European Journal |
DOI: | 10.1002/chem.202000635 |
Access Rights: | Open Access |
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10.1002_chem_202000635.pdf | 2.26 MB | Adobe PDF | ![]() |
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