High oxidation state bromocarbyne complexes
Date
2017
Authors
Hill, Anthony
Yuze Kong, Richard
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Royal Society of Chemistry
Abstract
Bromination of the carbyne complexes [W(RCR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(RCPh)Br3(dcpe)] and [W(RCBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.
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Chemical Communications
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Journal article
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Open Access
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Creative Commons Attribution-NonCommercial 3.0 Unported Licence
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