Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d 6 -metal alkynyl complexes
Date
2012
Authors
Drouet, Samuel
Merhi, Areej
Grelaud, Guillaume
Cifuentes, Marie
Matczyszyn, Katarzyna
Samoc, Marek
Toupet, L
Paul-Roth, Christine
Paul, Frederic
Humphrey, Mark
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Publisher
Royal Society of Chemistry
Abstract
The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds. This journal is
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Keywords
Keywords: alkynyl group; porphyrin; tetraphenylporphyrin derivative; unclassified drug; zinc tetraphenylporphyrin derivative; absorption; article; chemical structure; electron; priority journal; substitution reaction; synthesis; ultraviolet radiation; X ray crystal
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Source
New Journal of Chemistry
Type
Journal article
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2037-12-31
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