Wigner Near-Threshold Effects in the Photoelectron Angular Distribution of NO2-
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Laws, Benjamin; Cavanagh, Steven; Lewis, Brenton; Gibson, Stephen
Description
High-resolution velocity map imaged photoelectron spectra of the nitrite anion NO2- are measured over a range of photodetachment wavelengths between 355 and 550 nm, resolving the vibrational and rotational structure of the NO2(X̃2A1) + e- ← NO2-(X̃1A1) + hν transition. A full rotational band model is constructed to define the spectroscopic constants of both the neutral and the lesser studied anion ground states. The corresponding photoelectron angular distributions are characterized by a large...[Show more]
Collections | ANU Research Publications |
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Date published: | 2019-11-11 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/214097 |
Source: | Journal of Physical Chemistry A |
DOI: | 10.1021/acs.jpca.9b09073 |
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01_Laws_Wigner_Near-Threshold_Effects_2019.pdf | 1.1 MB | Adobe PDF | Request a copy |
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