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Synthesis and Properties of 2,3-Diethynyl-1,3-Butadienes

Sowden, Madison; Sherburn, Michael; Ward, James

Description

The first general preparative access to compounds of the 2,3-diethynyl-1,3-butadiene (DEBD) class is reported. The synthesis involves a one-pot, twofold Sonogashira-type, Pd 0 - catalyzed coupling of two terminal alkynes and a carbonate derivative of a 2-butyne-1,4-diol. The synthesis is broad in scope and members of this structural family are kinetically stable enough to be handled using standard laboratory techniques at ambient temperature. They decompose primarily through...[Show more]

CollectionsANU Research Publications
Date published: 2020
Type: Journal article
URI: http://hdl.handle.net/1885/211610
Source: Angewandte Chemie
DOI: 10.1002/anie.201914807

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