Skip navigation
Skip navigation

Ambient Temperature Transition-Metal-Free Dissociative Electron Transfer Reversible Addition–Fragmentation Chain Transfer Polymerization (DET-RAFT) of Methacrylates, Acrylates, and Styrene

Maximiano, Pedro; Mendonça, Patrícia V.; Costa, João R. C.; Haworth, Naomi; Serra, Arménio C.; Guliashvili, Tamaz; Coote, Michelle; Coelho, Jorge F. J.

Description

Inorganic sulfites as reducing agents were successfully used in combination with typical reversible addition− fragmentation chain transfer (RAFT) agents for the controlled DET-RAFT (DET: dissociative electron transfer) of methacrylates, methyl acrylate (MA), and styrene (Sty) near room temperature (30 °C). The polymerizations were first-order with respect to monomer conversion and polymers with narrow molecular weight distributions (Đ < 1.2), and “living” features were obtained. MALDI-TOF...[Show more]

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
URI: http://hdl.handle.net/1885/209209
Source: Macromolecules
DOI: 10.1021/acs.macromol.5b02647
Access Rights: Open Access

Download

File Description SizeFormat Image
Ambient Temperature.pdf576.61 kBAdobe PDFThumbnail


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator