Maximiano, Pedro; Mendonça, Patrícia V.; Costa, João R. C.; Haworth, Naomi; Serra, Arménio C.; Guliashvili, Tamaz; Coote, Michelle; Coelho, Jorge F. J.
Inorganic sulfites as reducing agents were successfully used in combination with typical reversible addition−
fragmentation chain transfer (RAFT) agents for the controlled
DET-RAFT (DET: dissociative electron transfer) of methacrylates, methyl acrylate (MA), and styrene (Sty) near room
temperature (30 °C). The polymerizations were first-order with
respect to monomer conversion and polymers with narrow
molecular weight distributions (Đ < 1.2), and “living” features
were obtained. MALDI-TOF...[Show more]
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.