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A Dirhoda-Heterocyclic Carbene

Barnett, Harrison; Hill, Anthony

Description

The linear m-carbido complex [Rh2(m-C)Cl2- (dppm)2] (dppm = bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2(m-C)(m-DMAD)Cl2(dppm)2], which features a bent RhCRh linkage (124.78) that might be described as a dirhoda-heterocyclic carbene, as demonstrated by coordination to further metal centers.

dc.contributor.authorBarnett, Harrison
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-09-01T00:52:05Z
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/1885/209158
dc.description.abstractThe linear m-carbido complex [Rh2(m-C)Cl2- (dppm)2] (dppm = bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2(m-C)(m-DMAD)Cl2(dppm)2], which features a bent RhCRh linkage (124.78) that might be described as a dirhoda-heterocyclic carbene, as demonstrated by coordination to further metal centers.
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP170102695 and DP190100723) for funding.
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherWiley-VCH Verlag GMBH
dc.rights© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.sourceAngewandte Chemie International Edition
dc.titleA Dirhoda-Heterocyclic Carbene
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume59
dc.date.issued2020
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationa383154xPUB10830
local.publisher.urlhttps://www.wiley.com/en-gb
local.type.statusAccepted Version
local.contributor.affiliationBarnett, Harrison, College of Science, ANU
local.contributor.affiliationHill, Anthony, College of Science, ANU
local.description.embargo2020-12-17
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723
local.bibliographicCitation.issue11
local.bibliographicCitation.startpage4274
local.bibliographicCitation.lastpage4277
local.identifier.doi10.1002/anie.201912650
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2020-05-10T08:17:15Z
dcterms.accessRightsOpen Access
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/1320..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).
CollectionsANU Research Publications

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