A Dirhoda-Heterocyclic Carbene
Date
2020
Authors
Barnett, Harrison
Hill, Anthony
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Wiley-VCH Verlag GMBH
Abstract
The linear m-carbido complex [Rh2(m-C)Cl2- (dppm)2] (dppm = bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2(m-C)(m-DMAD)Cl2(dppm)2], which features a bent RhCRh linkage (124.78) that might be described as a dirhoda-heterocyclic carbene, as demonstrated by coordination to further metal centers.
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Angewandte Chemie International Edition
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Journal article
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Open Access
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