Mechanical Stretching-Induced Electron-Transfer Reactions and Conductance Switching in Single Molecules

Date

2017

Authors

Li, Yueqi
Haworth, Naomi
Xiang, Limin
Ciampi, Simone
Coote, Michelle
Tao, Nongjian

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

A central idea in electron-transfer theories is the coupling of the electronic state of a molecule to its structure. Here we show experimentally that fine changes to molecular structures by mechanically stretching a single metal complex molecule via changing the metal-ligand bond length can shift its electronic energy levels and predictably guide electron-transfer reactions, leading to the changes in redox state. We monitor the redox state of the molecule by tracking its characteristic conductance, determine the shift in the redox potential due to mechanical stretching of the metal-ligand bond, and perform model calculations to provide insights into the observations. The work reveals that a mechanical force can shift the redox potential of a molecule, change its redox state, and thus allow the manipulation of single molecule conductance.

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Source

Journal of the American Chemical Society

Type

Journal article

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Access Statement

Open Access

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