Rational design of photo-cleavable alkoxyamines for polymerization and synthesis
Theoretical calculations have been performed in order to investigate the impact of different substitution patterns on predicted photoreactivity of alkoxyamines fused to an anthraquinone chromophore. Amino and hydroxy groups (similar to those which have been previously synthesized) are introduced and their effect on excited state energies and charge transfer is assessed. Analogous to formally oxidized alkoxyamines, the charge-separated nNπ* state can undergo mesolytic cleavage or bimolecular or...[Show more]
|Collections||ANU Research Publications|
|Source:||Physical chemistry chemical physics : PCCP|
|Access Rights:||Open Access|
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