The Synthesis, Structural Characterisation and Chemical Manipulation of the [6+3] Cycloadduct Derived from alpha-Tropolone O-Methyl Ether and Trimethylenemethane
Date
2019
Authors
Crisp, Antony
Noble, Dr Benjamin
Schwartz, Brett
Willis, Anthony
Coote, Michelle
Banwell, Martin
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Wiley
Abstract
The title bicyclic system 3, the adduct arising from the formal [6+3] cycloaddition of α‐tropolone O‐methyl ether (1) and trimethylenemethane (2), has been prepared and subject to single‐crystal X‐ray analysis. The chemical manipulation of adduct 3 in a range of ways is reported, including through acid‐catalysed rearrangement of the derived mono‐oxide to give the bicyclo[4.3.1]undecane 21.
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Asian Journal of Organic Chemistry
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Journal article
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Open Access
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