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Alkynylselenolatoalkylidynes (LnM C-Se-C CR) as building blocks for mixed metal/main-group extended frameworks

Frogley, Benjamin; Genet, Tobias; Hill, Anthony; Onn, Chee Sheng


The reactions of [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with lithium alkynylselenolates LiSeC[triple bond, length as m-dash]CR (R = SiMe3, SiiPr3, nBu, tBu, Ph, p-tolyl) afford the alkynylselenolatoalkylidyne complexes [W([triple bond, length as m-dash]CSeC[triple bond, length as m-dash]CR)(CO)2(Tp*)]. Desilylation of the SiMe3 complex furnishes the parent [W([triple bond, length as m-dash]CSeC[triple bond, length as...[Show more]

CollectionsANU Research Publications
Date published: 2019-04-29
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c9dt01504c
Access Rights: Open Access


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