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Computational Assessment of Verdazyl Derivatives for Electrochemical Generation of Carbon-Centered Radicals

Rogers, Fergus; Coote, Michelle

Description

To expand the scope for carbon-centered radical generation by electrochemical activation of adducts based on stable free radicals, a test set of six simple electron-rich Kuhn verdazyl derivatives in conjunction with nine different alkyl leaving groups has been computationally assessed. Like triazinyls, adducts of simple verdazyl derivatives functionalized with electron-donating substituents favor mesolytic cleavage to carbon-centered radicals under mild electrochemical potentials (−0.7 to −0.2...[Show more]

CollectionsANU Research Publications
Date published: 2019-07-23
Type: Journal article
URI: http://hdl.handle.net/1885/205876
Source: Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.9b06288

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