Computational Assessment of Verdazyl Derivatives for Electrochemical Generation of Carbon-Centered Radicals
To expand the scope for carbon-centered radical generation by electrochemical activation of adducts based on stable free radicals, a test set of six simple electron-rich Kuhn verdazyl derivatives in conjunction with nine different alkyl leaving groups has been computationally assessed. Like triazinyls, adducts of simple verdazyl derivatives functionalized with electron-donating substituents favor mesolytic cleavage to carbon-centered radicals under mild electrochemical potentials (−0.7 to −0.2...[Show more]
|Collections||ANU Research Publications|
|Source:||Journal of Physical Chemistry C|
|Access Rights:||Open Access|
|verdazyls_MS_revised.pdf||Author Accepted Manuscript||582.11 kB||Adobe PDF|
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