Rapid, Chemoenzymatic Syntheses of the Epoxyquinols (−)-Bromoxone Acetate and (−)-Tricholomenyn A
Date
2009
Authors
Pinkerton, David
Banwell, Martin
Willis, Anthony
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Publisher
CSIRO Publishing
Abstract
The epoxyquinol derivatives (-)-bromoxone acetate (ent-1) and (-)-tricholomenyn A (2) have been prepared from the cis-1,2-dihydrocatechols 3 and 4, respectively. Compounds 3 and 4 are themselves obtained in enantiomerically pure form through the whole-cell biotransformation of the corresponding halobenzene.
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Keywords
Keywords: Chemo-enzymatic synthesis; Epoxyquinol; Whole-cell biotransformations
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Source
Australian Journal of Chemistry
Type
Journal article
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Restricted until
2037-12-31
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