Skip navigation
Skip navigation

A [C-1 + C-2] route to propargylidyne complexes

Hill, Anthony; Manzano, Richard


The reactions of [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)] (Tp* = hydrotris(dimethylpyrazolyl)borate) with a range of terminal alkynes (RC[triple bond, length as m-dash]CH), mediated by [Pd(PPh3)4] and CuI, afford new proparylidynes [W([triple bond, length as m-dash]C–C[triple bond, length as m-dash]CR)(CO)2(Tp*)] [R = tBu, C6H4X (X = H, NH2, NO2), ferrocenyl, APh3 (A = C, Si, Ge), B(O2CCH2)2NMe]. Similar treatment of [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)] with Ph2Si(C[triple...[Show more]

CollectionsANU Research Publications
Date published: 2019-04-04
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c9dt00876d
Access Rights: Open Access


File Description SizeFormat Image
10.1039_c9dt00876d.pdf9.88 MBAdobe PDFThumbnail

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator