Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection
Date
2019
Authors
Zhang, Jinfang
Liu, Yuhang
Feng, Jiaoyang
Gong, Linpei
Humphrey, Mark
Zhang, Chi
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
A 3D heterothiometallic cluster-based metal−organic
framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8] 4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN− bridges. It possesses an unprecedented (3,11)-
connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media
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Source
Inorganic Chemistry
Type
Journal article
Book Title
Entity type
Access Statement
Open Access
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DOI
10.1021/acs.inorgchem.9b00745