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Synthesis, X-ray Structural Characterization, and DFT Calculations of Mononuclear Nickel(II) Complexes Containing Diamine and Methacrylate Ligands

Vafazadeh, Rasoul; Namazian, Mansoor; Shahpoori-Arani, Behnoosh; Willis, Anthony; Carr, Paul D


The mononuclear Ni(II) complexes [Ni(en)2(H2O)2](MAA)2 (1) and [Ni(pn)2(MAA)2] (2), where MAA, en and pn are methacrylate, ethylendiamine and 1,3-propylendiamine, respectively, have been synthesized and characterized by elemental analysis, FT-IR and UV–Vis spectroskopy. Structures of the complexes have been determined by single-crystal X-ray diffraction analyses. In the nickel(II) complexes 1 and 2 nickel(II) ion is six-coordinate and has a distorted octahedral geometry. Ni(II) is bonded to...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: Acta Chimica Slovenica
DOI: 10.17344/acsi.2017.4096
Access Rights: Open Access


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