Preparation, Structure, and Reactivity of Dipalladium(I) Complexes Containing the Carbanion 2?C6F4PPh2: Coexistence of Distinct, Noninterconverting Head-to-Head [Dipalladium(0/II)] and Head-to-Tail [Dipalladium(I)] Species
Date
2012
Authors
Bhargava, Suresh Kumar
Priver, Steven H
Willis, Anthony
Bennett, Martin
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American Chemical Society
Abstract
Comproportionation of trans-[Pd(κ 2-2-C 6F 4PPh 2) 2] with [PdL 4] (L = PPh 3, AsPh 3) gives metal-metal-bonded dipalladium(I) complexes [Pd 2I(μ-2-C 6F 4PPh 2) 2(L) 2] [L = PPh 3 (5), AsPh 3 (6)] in which the bridging ligands adopt a head-to-tail arran
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Keywords
Keywords: Binding modes; Bridging ligands; Dinuclear; In-situ; Iodobenzene; Metal atoms; Metal-metal distances; Metal-metal interactions; Methyl complexes; Methyl iodide; Mixed-valent; Oxidative additions; Palladium complexes; Reductive elimination; tert-Butyl isoc
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Organometallics
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Journal article
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2037-12-31
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