Skip navigation
Skip navigation

Alkali metal–alkaline earth metal borate crystal LiBa₃(OH)(B₉O₁₆)[B(OH)₄] as a new deep-UV nonlinear optical material

Wu, Chao; Song, Junling; Li, Longhua; Humphrey, Mark; Zhang, Chi


A new noncentrosymmetric alkali metal–alkaline earth metal borate with the formula LiBa₃(OH)(B₉O₁₆)[B(OH)₄] has been synthesized using a convenient hydrothermal method. The structure features a three-dimensional zeolite-like framework and consists of a [B₉O₁₉(OH)]¹²⁻ primary building unit with 6-membered-ring channels along the c-axis. The Ba dications and [B(OH)₄]− anions are encapsulated in the 6-membered-ring channels, while the Li cations are located between two adjacent [B9O19(OH)]¹²⁻...[Show more]

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
Source: Journal of Materials Chemistry C
DOI: 10.1039/C6TC02306A
Access Rights: Open Access


File Description SizeFormat Image
Alkali 2016.pdf4.29 MBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator