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Alkali metal–alkaline earth metal borate crystal LiBa₃(OH)(B₉O₁₆)[B(OH)₄] as a new deep-UV nonlinear optical material

Wu, Chao; Song, Junling; Li, Longhua; Humphrey, Mark; Zhang, Chi

Description

A new noncentrosymmetric alkali metal–alkaline earth metal borate with the formula LiBa₃(OH)(B₉O₁₆)[B(OH)₄] has been synthesized using a convenient hydrothermal method. The structure features a three-dimensional zeolite-like framework and consists of a [B₉O₁₉(OH)]¹²⁻ primary building unit with 6-membered-ring channels along the c-axis. The Ba dications and [B(OH)₄]− anions are encapsulated in the 6-membered-ring channels, while the Li cations are located between two adjacent [B9O19(OH)]¹²⁻...[Show more]

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
URI: http://hdl.handle.net/1885/148200
Source: Journal of Materials Chemistry C
DOI: 10.1039/C6TC02306A
Access Rights: Open Access

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