Alkali metal–alkaline earth metal borate crystal LiBa₃(OH)(B₉O₁₆)[B(OH)₄] as a new deep-UV nonlinear optical material
A new noncentrosymmetric alkali metal–alkaline earth metal borate with the formula LiBa₃(OH)(B₉O₁₆)[B(OH)₄] has been synthesized using a convenient hydrothermal method. The structure features a three-dimensional zeolite-like framework and consists of a [B₉O₁₉(OH)]¹²⁻ primary building unit with 6-membered-ring channels along the c-axis. The Ba dications and [B(OH)₄]− anions are encapsulated in the 6-membered-ring channels, while the Li cations are located between two adjacent [B9O19(OH)]¹²⁻...[Show more]
|Collections||ANU Research Publications|
|Source:||Journal of Materials Chemistry C|
|Access Rights:||Open Access|
|Alkali 2016.pdf||4.29 MB||Adobe PDF||Request a copy|
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