The relationship between mineral composition, crystal structure and paragenetic sequence: the case of secondary Te mineralization at the Bird Nest drift, Otto Mountain, California, USA
Date
2016
Authors
Christy, Andrew G.
Mills, Stuart J.
Kampf, Anthony R.
Housley, Robert M.
Thorne, Brent
Marty, Joe
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Mineralogical Society
Abstract
An unusually diverse array of 25 secondary Te oxysalt minerals has been documented from Otto Mountain, California, and 18 of these from the Bird Nest drift sublocality. A paragenetic sequence for these minerals is proposed, using observed overgrowth relationships plus spatial association data and data from other localities. Apart from Te and O, the components Pb, Cu and H are essential in the majority of the minerals. The atomic Cu/Te ratio decreases through the paragenetic sequence. This, and the occurrence of minerals with additional components such as Cl-, CO₃²⁻, SO₄²⁻ and Fe³⁺ at an intermediate stage, suggests nonmonotonic evolution of the parent fluids, reflecting differing access to or spatial distribution of various components. For the minerals with known crystal structures, two alternative 'structural units' were identified, one consisting only of the Te⁴⁺ or Te⁶⁺ oxyanion, while the other also included small, strongly-bound cations such as Cu²⁺. The degree of polymerization for the Te oxyanion correlated with the paragenetic sequence: the monomeric tellurate anions of early minerals were replaced progressively by dimers, chains and sheet structures, which may relate to a decreasing abundance of the 'network modifying' Cu²⁺ cation, analogous to Bowen's discontinuous reaction series in igneous rock-forming silicates. No relationship was seen between paragenetic order and the larger type of structural unit, or structural complexity as defined by information content. This contrasts with results in the literature for evaporite sulfates and pegmatite phosphates. While structure-paragenesis relationships may be widespread, the exact nature of such relationships may be different for different chemical systems and different paragenetic environments.
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Keywords
tellurate, tellurite, crystal structure, paragenetic sequence, complexity, secondary minerals, Otto Mountain, California
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Source
Mineralogical Magazine
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Journal article
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DOI
10.1180/minmag.2016.080.001