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Organometallic Complexes for Nonlinear Optics. 4. Cubic Hyperpolarizabilities of (Cyclopentadienyl)bis(phosphine)ruthenium σ-Arylacetylides

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Date

1995

Authors

Whittall, Ian R.
Humphrey, Mark G.
Samoc, Marek
Swiatkiewicz, Jacek
Luther-Davies, Barry

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Research Projects

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Abstract

Third-order molecular optical nonlinearities of a systematically varied series of (cyclopentadienyl)-bis(phosphine)ruthenium arylacetylide complexes have been determined by Z-scan and degenerate four-wave mixing techniques: the influence on the nonlinear response of replacing the acetylide by a chloro ligand, varying the phosphine, extending the acetylide chain length, or modifying the substituent at the 4-position of the arylacetylide has been studied.

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https://hdl.handle.net/1885/733803916

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ANU Research Publications

Source

Organometallics

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Journal article

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Publication

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DOI

10.1021/om00012a015

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