The coordination chemistry of iminooxosulphuranes: II. The interaction of tosyl-NSO with osmium-alkylidene complexes
Date
Authors
Herberhold, Max
Hill, Anthony F.
Journal Title
Journal ISSN
Volume Title
Publisher
Access Statement
Abstract
The low-valent osmium alkylidene complexes Os(=CHR)Cl(NO)(PPh3)2 (R = H, CO2Et) react with 4-tosyliminooxosulphurane, 4-MeC6H4SO2N=S=O, to give four-membered metallacyclic complexes which provide models for intermediates proposed in the pseudo-Wittig synthesis of alkylideniminosulphuranes from iminooxosulphuranes and phosphorous ylides.
Description
Keywords
Citation
Collections
Source
Journal of Organometallic Chemistry
Type
Book Title
Entity type
Publication