Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...
| dc.contributor.author | Bruce, Michael I. | en |
| dc.contributor.author | Dean, Christopher | en |
| dc.contributor.author | Duffy, D. Neil | en |
| dc.contributor.author | Humphrey, Mark G. | en |
| dc.contributor.author | Koutsantonis, George A. | en |
| dc.date.accessioned | 2026-01-07T10:40:38Z | |
| dc.date.available | 2026-01-07T10:40:38Z | |
| dc.date.issued | 1985-11-19 | en |
| dc.description.abstract | Title full: Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(CCPhNNC6H3Me2-3,4)(PPh3) 2(η-C5H5)][BF4] · 0.67CH2Cl2 and [Ru{CCPh(C7H7)}(DPPE)(η-C5H 5)][PF6] · 0.63CH2Cl2. Addition of arenediazonium or tropylium salts to Ru(C2Ph)(L)2(η-C5H5) (L2 = (PPh3)2 or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) Å for the aryldiazo complex, and 1.848(9) and 1.32(1) Å for the cycloheptatrienyl derivative. | en |
| dc.description.sponsorship | Acknowledgements. We thank Dr M.R. Snow for access to the X-ray diffractometer, Dr E. Horn for collecting the data set for complex 2, and the Australian Research Grants Scheme for financial support. CD and MGH are Commonwealth Post-Graduate Research awardees:. | en |
| dc.description.status | Peer-reviewed | en |
| dc.identifier.issn | 0022-328X | en |
| dc.identifier.other | ORCID:/0000-0002-4433-6783/work/162949500 | en |
| dc.identifier.scopus | 0002516959 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733803914 | |
| dc.language.iso | en | en |
| dc.source | Journal of Organometallic Chemistry | en |
| dc.title | Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of... | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | c44 | en |
| local.bibliographicCitation.startpage | c40 | en |
| local.contributor.affiliation | Bruce, Michael I.; University of Adelaide | en |
| local.contributor.affiliation | Dean, Christopher; University of Adelaide | en |
| local.contributor.affiliation | Duffy, D. Neil; University of Adelaide | en |
| local.contributor.affiliation | Humphrey, Mark G.; Jordan Laboratories | en |
| local.contributor.affiliation | Koutsantonis, George A.; University of Adelaide | en |
| local.identifier.citationvolume | 295 | en |
| local.identifier.doi | 10.1016/0022-328X(85)80329-6 | en |
| local.identifier.pure | 055d573c-0855-4af1-bc5f-455acaf3cf37 | en |
| local.identifier.url | https://www.scopus.com/pages/publications/0002516959 | en |
| local.type.status | Published | en |