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Self-assembly of a mixed-valence Fe<sup>II</sup>–Fe<sup>III</sup> tetranuclear star

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Sertphon, Darunee
Harding, Phimphaka
Murray, Keith S.
Moubaraki, Boujemaa
Chilton, Nicholas F.
Hill, Stephen
Marbey, Jonathan
Adams, Harry
Davies, Casey G.
Jameson, Guy N. L.

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A unique self-assembled mixed-valence FeII–FeIII tetranuclear star has been comprehensively characterised showing a large magnetic anisotropy at the peripheral FeII centres, ferromagnetic coupling between the iron centres and field-induced SMM behaviour.

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Dalton Transactions

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