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Unusual selectivity in the ring-opening of γ-valerolactone oxide by amines

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dc.contributor.authorMazloomi, Zahraen
dc.contributor.authorKallmeier, Fabianen
dc.contributor.authorKirchhecker, Sarahen
dc.contributor.authorStadler, Bernhard M.en
dc.contributor.authorPandey, Swechchhaen
dc.contributor.authorSchünemann, Claasen
dc.contributor.authorSpannenberg, Ankeen
dc.contributor.authorHering-Junghans, Christianen
dc.contributor.authorTin, Sergeyen
dc.contributor.authorde Vries, Johannes G.en
dc.contributor.authorBaráth, Eszteren
dc.date.accessioned2026-07-03T23:40:31Z
dc.date.available2026-07-03T23:40:31Z
dc.date.issued2023-06-13en
dc.description.abstractPrimary and secondary amines selectively react with the lactone moiety of γ-valerolactone oxide (GVLO). Several primary amines afforded the resulting epoxyamides with an intact epoxy group. In some cases addition of two equivalents of amine resulted in additional epoxide opening to give α,γ-dihydroxy-β-amino-amides. The selective lactone-opening in GVLO was further corroborated by DFT-studies.en
dc.description.statusPeer-revieweden
dc.format.extent4en
dc.identifier.issn1359-7345en
dc.identifier.otherPubMed:37337749en
dc.identifier.otherORCID:/0000-0001-7073-2766/work/219173118en
dc.identifier.scopus85163975548en
dc.identifier.urihttps://hdl.handle.net/1885/733812786
dc.language.isoenen
dc.rightsPublisher Copyright: © 2023 The Royal Society of Chemistry.en
dc.sourceChemical Communicationsen
dc.titleUnusual selectivity in the ring-opening of γ-valerolactone oxide by aminesen
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage8447en
local.bibliographicCitation.startpage8444en
local.contributor.affiliationMazloomi, Zahra; Leibniz Institute for Catalysisen
local.contributor.affiliationKallmeier, Fabian; Leibniz Institute for Catalysisen
local.contributor.affiliationKirchhecker, Sarah; Leibniz Institute for Catalysisen
local.contributor.affiliationStadler, Bernhard M.; Leibniz Institute for Catalysisen
local.contributor.affiliationPandey, Swechchha; Leibniz Institute for Catalysisen
local.contributor.affiliationSchünemann, Claas; Leibniz Institute for Catalysisen
local.contributor.affiliationSpannenberg, Anke; Leibniz Institute for Catalysisen
local.contributor.affiliationHering-Junghans, Christian; Leibniz Institute for Catalysisen
local.contributor.affiliationTin, Sergey; Leibniz Institute for Catalysisen
local.contributor.affiliationde Vries, Johannes G.; Leibniz Institute for Catalysisen
local.contributor.affiliationBaráth, Eszter; Leibniz Institute for Catalysisen
local.identifier.citationvolume59en
local.identifier.doi10.1039/d3cc01957hen
local.identifier.pure884aa06a-df30-4805-9e73-89e8139cafe4en
local.identifier.urlhttps://www.scopus.com/pages/publications/85163975548en
local.type.statusPublisheden

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