trans-dichlorobis[(R,R)-1,2-phenylenebis-(methylphenylphosphine-P)] ruthenium(II)
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Hockless, David C.R.
Wild, S. Bruce
Mcdonagh, Andrew M.
Whittall, Ian R.
Humphrey, Mark G.
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Abstract
The title complex, [RuCl2(C20H20P2)2]. is a convenient precursor for the synthesis of interesting symmetrical or unsymmetrical optically active ruthenium σ-acetylide complexes. The complex has trans geometry about the octahedral Ru atom, with Ru - P distances in the range 2.304 (1)-2.354 (1) Å and Ru - Cl distances of 2.426 (1) and 2.432 (1) Å.
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Acta Crystallographica Section C: Crystal Structure Communications
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